Frederic Mentink-Vigier

Visiting Research Faculty I



Contact Information

Phone (850) 644-1189
Fax (850) 644-1366
Address 1800 E. Paul Dirac Dr.
Tallahassee , FL 32310-3706
Building NHMFL FSU

Publications and Scientific Activities


    1. De novo prediction of cross-effect efficiency for magic angle spinning dynamic nuclear polarization Mentink-Vigier, F.; Barra, A.L.; van Tol, J.; Hediger, S.; Lee, D.; De Paepe, G. Phys. Chem. Chem. Phys., -, -, 14 (2019)


    1. A quasi-optical and corrugated waveguide microwave transmission system for simultaneous dynamic nuclear polarization NMR on two separate 14.1 T spectrometers Dubroca, T.; Smith, A.N.; Pike, K.J.; Froud, S.; Wylde, R.; Trociewitz, B.; McKay, J.; Mentink-Vigier, F.; van Tol, J.; Wi, S.; Brey, W.; Long, J.R.; Frydman, L.; Hill, S. J. Magn. Reson., 289, 35-44 (2018)
    2. Exploring Applications of Covalent Organic Frameworks: Homogeneous Reticulation of Radicals for Dynamic Nuclear Polarization Cao, W.; Wang, W.D.; Xu, H.S.; Sergeyev, I.V.; Struppe, J.; Wang, X.; Mentink-Vigier, F.; Gan, Z.; Xiao, M.X.; Wang, L.Y.; Chen, G.P.; Ding, S.Y.; Bai, S.; Wang, W. J. Am. Chem. Soc., 141, 6969–6977 (2018)
    3. The “Missing” Bicarbonate in CO2 Chemisorption Reactions on Solid Amine Sorbents Chen, C.H.; Shimon, D.; Lee, J.J.; Mentink-Vigier, F.; Hung, I.; Siever, C.W.; Jones, C.; Hayes, S.E. J. Am. Chem. Soc., 140, 28, 8648-8651 (2018)
    4. Molecular architecture of fungal cell walls revealed by solid-state NMR Kang, X.; Kirui, A.; Muszyński, A.; Widanage, M.C.D.; Chen, A.; Azadi, P.; Wang, P.; Mentink-Vigier, F.; Wang, T. Nature Comm., 9, 1, 2747 (2018)
    5. Computationally Assisted Design of Polarizing Agents for Dynamic Nuclear Polarization Enhanced NMR: The AsymPol Family Mentink-Vigier, F.; Marin-Montesinos, I.; Jagtap, A.P.; Halbritter, T.; van Tol, J.; Hediger, S.; Lee, D.; Sigurdsson, S.TH.; De Paepe, G. J. Am. Chem. Soc., 140, 35, 11013-11019 (2018)
    6. Atomic resolution of cotton cellulose structure enabled by dynamic nuclear polarization solid-state NMR Kirui, A.; Ling, X.K.; Dickwella Widanage, M.C.; Mentink-Vigier, F.; French, A.D.; Wang, T. Cellulose, n.c., n.c. (2018)
    7. MAS-DNP Enhancements: Hyperpolarization, Depolarization, and Absolute Sensitivity Hediger, S.; Lee, D.; Mentink-Vigier, F.; De Paepe, G. eMagRes, 7, 105–116 (2018)
    8. Spin Dynamics and MAS-DNP: theory and experiments Mentink-Vigier, F.; Vega, S. and De Paepe, G. EUROMAR Nantes, France July 1st-5th (2018)
    9. DNP in solids: History, Theory and Applications Mentink-Vigier, F. 14th International Bologna Conference on Magnetic Resonance in Porous Media (MRPM14) Gainesville, Florida, United States February, 17th (2018)
    10. AsymPol: a family of simple asymmetric bis-nitroxides for efficient Cross-Effect MAS-DNP Mentink-Vigier, F.; Marin-Montesinos, I.; Jagtap, A.P.; Halbritter, T.; Van Tol, J.; Hediger, S.;Lee, D.; Sigurdsson, S. Th. and De Paepe, G. 59th Experimental Nuclear Magnetic Resonance Orlando, Florida, United States April 29 - May 4th (2018)
    11. High Enhancement and Large Volume Overhauser Liquid DNP at 14.1 T Dubroca, T.; van Tol, J; Trociewitz, B.; Mentink-Vigier, F.; Wi, S.; Brey, W.; Frydman, L; Long, J.R. and Hill, S. Hyperpolarization conference Southhampton, United Kingdom September (2018)
    12. Overhauser liquid Dynamic Nuclear Polarization and in-situ Electron Paramagnetic Resonance at 14.1 T - 395 GHz Dubroca, T.; van Tol, J.; Trociewitz, B.; Mentink-Vigier, F.; Wi, S.; Brey, W.; Frydman, L.; Long, J.R. and Hill S. Experimental NMR conference Orlando, Florida, United States April (2018)


    1. Persistent Radicals of Self-assembled Benzophenone bis-urea Macrocycles: Characterization and Application as a Polarizing Agent for Solid-state DNP MAS Spectroscopy DeHaven, B.A.; Tokarski, J.T. III.; Korous, A.A.; Mentink-Vigier, F.; Makris, T.M.; Brugh, A.M.; Forbes, M.D.E.; van Tol, J.; Bowers, C.R.; Shimizu, L.S. Chem. Eur. J., 23, 1-6 (2017)
    2. Efficient Cross-Effect Dynamic Nuclear Polarization without Depolarization in High-resolution MAS NMR Mentink-Vigier, F.; Mathies, G.; Liu, Y.; Barra, A.-L.; Caporini, M.; Lee, D.; Hediger, S.; Griffin, R.G. and De Paëpe, G. Chem. Sci., 8, 8150-8163 (2017)
    3. One step closer towards in silico biradical design(…for MAS-DNP) Mentink-Vigier, F.; Lee, D.; Barra, A-L.; van Tol, J.; Hediger, S.; Vega S. and De Paëpe, G. ISMAR Quebec July, 23-28th (2017)
    4. Towards in silico radical design for MAS-DNP Mentink-Vigier, F; Vega, S.; van Tol, H.; Lee, D.; Hediger, S. and De Paëpe, G. 46th Southeastern Magnetic Resonance Conference Tallahassee, Florida, United States October, 27-29th (2017)