Researchers have discovered a new method to create encapsulated carbon nanomaterials that contain fluorine. Known as fullerenes, these nanocages are promising candidates for clean energy applications.
This research established experimental evidence for the long sought-after transition of a small, two-dimensional sheet of electrons to a solid state.
In this study, researchers added a low concentration of the endohedral metallofullerene (EMF) Gd2@C79N to DNP samples, finding that 1H and 13C enhancements increased by 40% and 50%, respectively, at 5 teslas and 1.2 Kelvin.
Analogous to the unique spectral fingerprint of any atom or molecule, researchers have measured the spectrum of optical excitations in monolayer tungsten diselenide (WSe2), which is a member of a new family of ultrathin semiconductors that are just one atomic layer thick.
A unique way to bond together single-layer semiconductors opens a door to new nanotechnologies.
Paul Dunk, a chemist in the MagLab's Ion Cyclotron Resonance Facility, has published a paper on so-called "nanocages" formed by combining graphite, a two-dimensional form of carbon, with different metals. The research, Transformation of doped graphite into cluster-encapsulated fullerene cages, appeared this week in Nature Communications.
For the research, Dunk and his collaborators created metallofullerenes, molecules that consist of a ball-like carbon structure that encompasses several atoms inside of it — hence the term "nanocage."
Dunk and his colleagues tested theories of how these compounds form by looking for hypothesized intermediate molecules between the original reactants and end products. They demonstrated that, unlike what many scientists believed, the cages do not shrink from or break off of larger globs of carbon, but rather nucleate around the metal, carbon atom by carbon atom.
The findings could help in the future development of nanocage-related technologies ranging from new light-based electronics to molecular electronics.
Dunk's research was done in collaboration with scientists at the Universitat Rovira i Virgili in Spain and the University of Texas at El Paso.
Read more about this research in the MagLab's fields magazine.
Image of nanocages by Paul Dunk/Caroline McNiel.
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