EMR Science Highlights
Vibronic Coupling in a Molecular Magnet
Using far-infared magnetospectroscopy in high magnetic fields, scientists probed coupled electronic and vibrational modes in a molecular magnet that are of interest in future classical and quantum information applications.
Isolation of a Triplet Benzene Dianion
High-magnetic-field, high-frequency electron paramagnetic resonance demonstrates how coordination chemistry can be leveraged to stabilize a desired electronic/magnetic state in an organic molecule. In this experiment, the long-sought magnetic (triplet) ground state in a benzene ring is stabilized by a pair of metal ions above and below the six-carbon ring.
Magnetoelastic Coupling in the Multiferroic BiFeO3
High-resolution electron magnetic resonance studies of the spin-wave spectrum in the high-field phase of the multiferroic Bismuth ferrite (BiFeO3) reveal direct evidence for the magnetoelastic coupling through a change in lattice symmetry from rhombohedral to monoclinic. This study provides important information for designing future spintronics devices based on BiFeO3.
Strong Magnetic Coupling in Molecular Magnets through Direct Metal-Metal Bonds
An exciting advance of interest to future molecular-scale information storage. By using the uniquely high frequency Electron Magnetic Resonance techniques available at the MagLab, researchers have found single molecule magnets that feature direct metal orbital overlap (instead of weak superexchange interactions), resulting in behavior similar to metallic feromagnets that is far more suitable to future technologies than previous molecular magnets.
Spin-Charge Interconversion at Near-Terahertz Frequencies
This work reports the first observation of the dynamical generation of a spin polarized current from an antiferromagnetic material into an adjacent non-magnetic material and its subsequent conversion into electrical signals
Molecular magnetic building blocks
This study reports the first transition metal compounds featuring mixed fluoride–cyanide ligands. A significant enhancement of the magnetic anisotropy, as compared to the pure fluoride ligated compounds, is demonstrated by combined analysis of high-field electron paramagnetic resonance (HF-EPR) spectroscopy and magnetization measurements.
Nuclear Spin Patterning Controls Electron Spin Coherence
Electron spin resonance work shows how transition metal can retain quantum information, important work on the path to next-generation quantum technologies.
Liquid State Dynamic Nuclear Polarization at High Magnetic Field
This finding demonstrates a path forward to dramatically enhance sensitivity for molecule concentration measurement by magnetic resonance using Overhauser DNP.
![Scientists studied the copper-based compound [Cu(pyrimidine)H2O4] SiF6 H2O. Repeating units of four copper ions (see above) create corkscrew-like chains with intriguing magnetic properties.](/media/k2/items/cache/27646697e277dff903d4ed00b18ff78b_S.jpg)
High field uncovers magnetic properties in chains of copper ions
The findings contribute to scientists' understanding of magnetic materials that could point the way to future applications.
Scientists observe molecular movements in T cells
Insights into the structure and movement of T cell surface proteins could lead to new ways to fight cancers, infections and other diseases.
Making a non-heme oxoiron(IV) complex a better oxidant
This work investigates a series of oxoiron complexes that serve as models towards understanding the mechanism of catalysis for certain iron-containing enzymes.
Novel metallofullerene boosts dynamic nuclear polarization
In this study, researchers added a low concentration of the endohedral metallofullerene (EMF) Gd2@C79N to DNP samples, finding that 1H and 13C enhancements increased by 40% and 50%, respectively, at 5 teslas and 1.2 Kelvin.
Across the Tree of Life: Radiation Resistance Gauged by High-Field EPR
This high-field EPR study of the H-Mn2+ content in the bacterium Deinococcus Radiodurans provides the strongest known biological indicator of cellular ionizing radiation resistance between and within the three domains of the tree of life, with potential applications including optimization of radiotherapy.
Reversible magnetic switching in multifunctional material
With just a drop of water, a cobalt-based material changes both color and magnetic properties.
![Representative high-field EPR data and structural details of the (PPh4)2[Co(SPh)4] molecule.](/media/k2/items/cache/1706b33fef7712ba31cca5e36abb2536_S.jpg)
Magneto-structural correlations in a transition metal complex
In the field of inorganic chemistry, magneto-structural correlations have been used to rationally design molecules with desirable properties, and to relate these properties to the electronic and geometric structures. In turn, such studies provide powerful tools for understanding important catalytic processes, as well as elucidating the structures of active sites in metalloproteins. This study reveals an unusually strong sensitivity of the magnetic properties of a CoS4 molecule to minute changes in its structure.
Symmetry reduction in a quantum kagomé antiferromagnet
This area of research could help scientists understand high-temperature superconductivity and other mysteries.
Potential qubits maintain quantum coherence outside a crystal
This approach to building “qubits” could be a promising tool for developing quantum computers.
New record magnetic anisotropy in a molecular nanomagnet
Scientists created a molecular nanomagnet based on a single nickel atom with record-high magnetic anisotropy — a quality that makes it a promising building block for applications like memory storage.
Tweaking molecular structure to tune chemical reactivity
A recent high-field EPR study by MagLab users from Wayne State and Grand Valley State Universities has demonstrated that minor changes in the periphery of a nickel-containing molecule can lead to a dramatic reorganization of its electron distribution. This in turn, induces a major shift in the reactivity of this compound.
An approach for dynamic nuclear polarization of membrane proteins
Dynamic nuclear polarization (DNP) coupled with solid state NMR can provide orders of magnitude enhancement to normally weak NMR signals, thereby enabling the study of inherently dilute proteins such as membrane proteins. Here we demonstrate a new approach to obtain DNP signal enhancements of membrane proteins by utilizing spin labeled lipids as the polarization agents. This strategy results in more than 2x in signal enhancements of a membrane protein when compared to standard DNP sample preparation techniques.
